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Highly Enantioselective Hydrogenation of Enamides Catalyzed by Chiral Phosphoric Acids
[Figure: see text] A highly enantioselective hydrogenation of enamides catalyzed by a dual chiral-achiral acid system was developed. By employing a sub-stoichiometric amount of a chiral phosphoric acid and acetic acid, catalyst loadings as low as 1 mol% of the chiral catalyst were sufficient to prov...
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| Main Authors: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2009
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2765520/ https://ncbi.nlm.nih.gov/pubmed/19199770 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802860u |
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