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Highly Enantioselective Iridium‐Catalyzed Hydrogenation of Cyclic Enamides

The MaxPHOX–Ir catalyst system provided the highest selectivity ever reported for the reduction of cyclic enamides derived from α‐ and β‐tetralones. This result indicates that iridium catalysts are also proficient in reducing alkenes bearing metal‐coordinating groups. In the present system, selectiv...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Salomó, Ernest, Orgué, Sílvia, Riera, Antoni, Verdaguer, Xavier
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5084810/
https://ncbi.nlm.nih.gov/pubmed/27186653
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201602219
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