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Origins of Stereoselectivities in Chiral Phosphoric Acid-Catalyzed Allylborations and Propargylations of Aldehydes

The chiral BINOL-phosphoric acid catalyzed allylboration and propargylation reactions are studied with density functional theory (B3LYP and B3LYP-D3). Two different models were recently proposed for these reactions by Goodman and our group, respectively. In Goodman's model for allylborations, t...

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Hlavní autoři: Wang, Hao, Jain, Pankaj, Antilla, Jon C., Houk, K. N.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3568159/
https://ncbi.nlm.nih.gov/pubmed/23298338
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo302787m
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