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Mechanistic Studies on RNA Strand Scission From a C2′-Radical
The C2′-carbon hydrogen bond in ribonucleotides is significantly weaker than other carbohydrate carbon-hydrogen bonds in RNA or DNA. Independent generation of the C2′-uridine radical (1) in RNA oligonucleotides via Norrish Type I photocleavage of a ketone substituted nucleotide yields direct strand...
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| I publikationen: | J Org Chem |
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| Huvudupphovsmän: | , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2016
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5055465/ https://ncbi.nlm.nih.gov/pubmed/27668445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b01760 |
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