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Structural diversity of halocarbonyl molybdenum and tungsten PNP pincer complexes through ligand modifications

This work presents a comparative study of a series of halocarbonyl Mo(ii) and W(ii) complexes of the types [M(PNP)(CO)(3)X]X and [M(PNP)(CO)(2)X(2)] (M = Mo, W; X = I, Br), featuring PNP pincer ligands based on a 2,6-diaminopyridine scaffold. The complexes were prepared and fully characterized. The...

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Publicat a:Dalton Trans
Autors principals: de Aguiar, Sara R. M. M., Stöger, Berthold, Pittenauer, Ernst, Allmaier, Günter, Veiros, Luis F., Kirchner, Karl
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5048400/
https://ncbi.nlm.nih.gov/pubmed/27513832
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6dt02251k
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