Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation

[Image: see text] The bis-carbonyl Fe(II) complex trans-[Fe(PNP-iPr)(CO)(2)Cl](+) reacts with Zn as reducing agent under a dihydrogen atmosphere to give the Fe(II) hydride complex cis-[Fe(PNP-iPr)(CO)(2)H](+) in 97% isolated yield. A crucial step in this reaction seems to be the reduction of the aci...

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Bibliographic Details
Main Authors: Bichler, Bernhard, Holzhacker, Christian, Stöger, Berthold, Puchberger, Michael, Veiros, Luis F., Kirchner, Karl
Format: Artigo
Language:Inglês
Published: American Chemical Society 2013
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3751463/
https://ncbi.nlm.nih.gov/pubmed/23990692
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400241x
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