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Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation
[Image: see text] The bis-carbonyl Fe(II) complex trans-[Fe(PNP-iPr)(CO)(2)Cl](+) reacts with Zn as reducing agent under a dihydrogen atmosphere to give the Fe(II) hydride complex cis-[Fe(PNP-iPr)(CO)(2)H](+) in 97% isolated yield. A crucial step in this reaction seems to be the reduction of the aci...
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| Autors principals: | , , , , , |
|---|---|
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American
Chemical Society
2013
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| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3751463/ https://ncbi.nlm.nih.gov/pubmed/23990692 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400241x |
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