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Synthesis and reactivity of BINEPINE-based chiral Fe(II) PNP pincer complexes
ABSTRACT: A new asymmetric chiral PNP ligand based on the 2,6-diaminopyridine scaffold featuring a R-BINEPINE moiety was prepared. Treatment of anhydrous FeX(2) (X = Cl, Br) with 1 equiv of PNP-iPr,BIN at room temperature afforded the coordinatively unsaturated paramagnetic complexes [Fe(PNP-iPr,BIN...
Guardat en:
| Publicat a: | Monatsh Chem |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Springer Vienna
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4869728/ https://ncbi.nlm.nih.gov/pubmed/27340297 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-016-1706-x |
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