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Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism
[Image: see text] We have prepared and structurally characterized a new class of Fe(II) PNP pincer hydride complexes [Fe(PNP-iPr)(H)(CO)(L)](n) (L = Br(–), CH(3)CN, pyridine, PMe(3), SCN(–), CO, BH(4)(–); n = 0, +1) based on the 2,6-diaminopyridine scaffold where the PiPr(2) moieties of the PNP liga...
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Publicado no: | Organometallics |
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Main Authors: | , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
American
Chemical Society
2014
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Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5021386/ https://ncbi.nlm.nih.gov/pubmed/27642211 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5009814 |
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