Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism

[Image: see text] We have prepared and structurally characterized a new class of Fe(II) PNP pincer hydride complexes [Fe(PNP-iPr)(H)(CO)(L)](n) (L = Br(–), CH(3)CN, pyridine, PMe(3), SCN(–), CO, BH(4)(–); n = 0, +1) based on the 2,6-diaminopyridine scaffold where the PiPr(2) moieties of the PNP liga...

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Détails bibliographiques
Publié dans:Organometallics
Auteurs principaux: Gorgas, Nikolaus, Stöger, Berthold, Veiros, Luis F., Pittenauer, Ernst, Allmaier, Günter, Kirchner, Karl
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2014
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5021386/
https://ncbi.nlm.nih.gov/pubmed/27642211
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5009814
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