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A complete series of halocarbonyl molybdenum PNP pincer complexes – Unexpected differences between NH and NMe spacers
In the present study a complete series of seven-coordinate neutral halocarbonyl Mo(II) complexes of the type [Mo(PNP(Me)-Ph)(CO)(2)X(2)] (X = I, Br, Cl, F), featuring the new PNP pincer ligand N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine (PNP(Me)-Ph), were prepared and fully character...
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Main Authors: | , , , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Elsevier Sequoia
2014
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4004049/ https://ncbi.nlm.nih.gov/pubmed/24940004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2013.12.018 |
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