A complete series of halocarbonyl molybdenum PNP pincer complexes – Unexpected differences between NH and NMe spacers

In the present study a complete series of seven-coordinate neutral halocarbonyl Mo(II) complexes of the type [Mo(PNP(Me)-Ph)(CO)(2)X(2)] (X = I, Br, Cl, F), featuring the new PNP pincer ligand N,N′-bis(diphenylphosphino)-N,N′-methyl-2,6-diaminopyridine (PNP(Me)-Ph), were prepared and fully character...

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Main Authors: de Aguiar, Sara Raquel M.M., Stöger, Berthold, Pittenauer, Ernst, Puchberger, Michael, Allmaier, Günter, Veiros, Luis F., Kirchner, Karl
Formáid: Artigo
Teanga:Inglês
Foilsithe: Elsevier Sequoia 2014
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Article
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4004049/
https://ncbi.nlm.nih.gov/pubmed/24940004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jorganchem.2013.12.018
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