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Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes: Interplay between Water and Molecular Oxygen
The synthesis of cationic mono oxo Mo(IV) PNP pincer complexes of the type [Mo(PNP(Me)‐iPr)(O)X](+) (X = I, Br) from [Mo(PNP(Me)‐iPr)(CO)X(2)] is described. These compounds are coordinatively unsaturated and feature a strong Mo≡O triple bond. The formation of these complexes proceeds via cationic 14...
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| Publicado no: | Eur J Inorg Chem |
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| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6485545/ https://ncbi.nlm.nih.gov/pubmed/31057330 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201701413 |
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