Formation of Mono Oxo Molybdenum(IV) PNP Pincer Complexes: Interplay between Water and Molecular Oxygen

The synthesis of cationic mono oxo Mo(IV) PNP pincer complexes of the type [Mo(PNP(Me)‐iPr)(O)X](+) (X = I, Br) from [Mo(PNP(Me)‐iPr)(CO)X(2)] is described. These compounds are coordinatively unsaturated and feature a strong Mo≡O triple bond. The formation of these complexes proceeds via cationic 14...

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Publicat a:Eur J Inorg Chem
Autors principals: de Aguiar, Sara R. M. M., Öztopcu, Özgür, Troiani, Anna, de Petris, Giulia, Weil, Matthias, Stöger, Berthold, Pittenauer, Ernst, Allmaier, Günter, Veiros, Luis F., Kirchner, Karl
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6485545/
https://ncbi.nlm.nih.gov/pubmed/31057330
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201701413
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