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Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

Hydrogenase enzymes efficiently process H(2) and protons at organometallic FeFe, NiFe, or Fe active sites. Synthetic modeling of the many H(2)ase states has provided insight into H(2)ase structure and mechanism, as well as afforded catalysts for the H(2) energy vector. Particularly important are hyd...

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Detalhes bibliográficos
Publicado no:Chem Rev
Main Authors: Schilter, David, Camara, James M., Huynh, Mioy T., Hammes-Schiffer, Sharon, Rauchfuss, Thomas B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5026416/
https://ncbi.nlm.nih.gov/pubmed/27353631
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemrev.6b00180
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