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Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

Hydrogenase enzymes efficiently process H(2) and protons at organometallic FeFe, NiFe, or Fe active sites. Synthetic modeling of the many H(2)ase states has provided insight into H(2)ase structure and mechanism, as well as afforded catalysts for the H(2) energy vector. Particularly important are hyd...

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Bibliographische Detailangaben
Veröffentlicht in:Chem Rev
Hauptverfasser: Schilter, David, Camara, James M., Huynh, Mioy T., Hammes-Schiffer, Sharon, Rauchfuss, Thomas B.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2016
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5026416/
https://ncbi.nlm.nih.gov/pubmed/27353631
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemrev.6b00180
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