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Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

Hydrogenase enzymes efficiently process H(2) and protons at organometallic FeFe, NiFe, or Fe active sites. Synthetic modeling of the many H(2)ase states has provided insight into H(2)ase structure and mechanism, as well as afforded catalysts for the H(2) energy vector. Particularly important are hyd...

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Bibliographic Details
Published in:Chem Rev
Main Authors: Schilter, David, Camara, James M., Huynh, Mioy T., Hammes-Schiffer, Sharon, Rauchfuss, Thomas B.
Format: Artigo
Language:Inglês
Published: 2016
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5026416/
https://ncbi.nlm.nih.gov/pubmed/27353631
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemrev.6b00180
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