Загрузка...

Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel

[Image: see text] Theory and experiment indicate that the protonation of reduced NiFe dithiolates proceeds via a previously undetected isomer with enhanced basicity. In particular, it is proposed that protonation of (OC)(3)Fe(pdt)Ni(dppe) (1; pdt(2–) = (–)S(CH(2))(3)S(–); dppe = Ph(2)P(CH(2))(2)PPh(...

Полное описание

Сохранить в:
Библиографические подробности
Главные авторы: Huynh, Mioy T., Schilter, David, Hammes-Schiffer, Sharon, Rauchfuss, Thomas B.
Формат: Artigo
Язык:Inglês
Опубликовано: American Chemical Society 2014
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC4156870/
https://ncbi.nlm.nih.gov/pubmed/25094041
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja505783z
Метки: Добавить метку
Нет меток, Требуется 1-ая метка записи!