Caricamento...
Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds
We describe an enantioseleclive silylation of cyclopropanes catalyzed by a rhodium precursor and the bisphosphine (S)-DTBM-SEGPHOS. (Hydrido)silyl ethers, generated in situ by the dehydrogenative silylation of cyclopropylmethanols with diethylsilane, undergo asymmetric, intramolecular silylation of...
Salvato in:
| Pubblicato in: | Angew Chem Int Ed Engl |
|---|---|
| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
|
| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4976637/ https://ncbi.nlm.nih.gov/pubmed/27253898 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603153 |
| Tags: |
Aggiungi Tag
Nessun Tag, puoi essere il primo ad aggiungerne! !
|