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Photochemical Generation of a Tryptophan Radical within the Subunit Interface of Ribonucleotide Reductase
The E. coli class Ia ribonucleotide reductase (RNR) achieves forward and reverse proton-coupled electron transfer (PCET) over a pathway of redox-active amino acids (β-Y(122) ⇌ β-Y(356) ⇌ α-Y(731) ⇌ α-Y(730) ⇌ α-C(439)) spanning ~35 Å and two subunits every time it turns over. We have developed photo...
Enregistré dans:
| Publié dans: | Biochemistry |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4929995/ https://ncbi.nlm.nih.gov/pubmed/27159163 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.6b00292 |
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