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Enantioselective Rh-catalyzed Carboacylation of C=N Bonds via C–C Activation of Benzocyclobutenones
Herein we describe the first enantioselective Rh-catalyzed carboacylation of oximes (imines) via C–C activation. In this transformation, the benzocyclobutenone C1–C2 bond is selectively activated by a low valent rhodium catalyst and subsequently the resulting two Rh–C bonds add across a C=N bond, wh...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4884656/ https://ncbi.nlm.nih.gov/pubmed/26674855 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b11120 |
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