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Rh-catalyzed reagent-free ring expansion of cyclobutenones and benzocyclobutenones
Here we report a reagent-free rhodium-catalyzed ring-expansion reaction via C–C cleavage of cyclobutenones. A variety of poly-substituted cyclopentenones and 1-indanones can be synthesized from simple cyclobutenones and benzocyclobutenones. The reaction condition is near pH neutral without additiona...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5201212/ https://ncbi.nlm.nih.gov/pubmed/28042458 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc01875g |
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