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Cobalt-Catalyzed Intramolecular Alkyne/Benzocyclobutenone Coupling: C–C Bond Cleavage via a Tetrahedral Dicobalt Intermediate
A Co(0)-catalyzed intramolecular alkyne/benzocyclobutenone coupling through C–C cleavage of benzocyclobutenones is described. Co(2)(CO)(8)/P[3, 5-(CF(3))(2)C(6)H(3)](3) was discovered to be an effective metal/ligand combination, which exhibits complementary catalytic activity to the previously estab...
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| Publicado no: | ACS Catal |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5983384/ https://ncbi.nlm.nih.gov/pubmed/29868245 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b03852 |
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