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Preparation, Characterization, and Oxygenase Activity of a Photocatalytic Artificial Enzyme

A bicyclo[6,1,0]nonyne-substituted 9-mesityl-10-methyl-acridinium cofactor was prepared and covalently linked to a prolyl oligopeptidase scaffold containing a genetically encoded 4-azido-L-phenylalanine residue in its active site. The resulting artificial enzyme catalyzed sulfoxidation when irradiat...

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Detalhes bibliográficos
Publicado no:Chembiochem
Main Authors: Gu, Yifan, Ellis-Guardiola, Ken, Srivastava, Poonam, Lewis, Jared C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4873458/
https://ncbi.nlm.nih.gov/pubmed/26097041
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.201500165
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