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Total Synthesis of (−)-Chromodorolide B
The first total synthesis of a chromodorolide diterpenoid is described. The synthesis features a bimolecular radical addition/cyclization/fragmentation cascade that unites butenolide and trans-hydrindane fragments while fashioning two C–C bonds and stereoselectively forming three of the ten contiguo...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4864965/ https://ncbi.nlm.nih.gov/pubmed/26880210 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b00541 |
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