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Enantioselective Total Synthesis of Aplyviolene

The enantioselective total synthesis of the rearranged spongian diterpene aplyviolene has been completed in 14 steps from the known hydroazulenone 8. The key junction of the hydrocarbon and oxygenated fragments to form the critical C8 quaternary carbon stereocenter and set the stage for elaborating...

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Autori principali: Overman, Larry E., Schnermann, Martin J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3205941/
https://ncbi.nlm.nih.gov/pubmed/21936525
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208018s
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