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Enantioselective Total Synthesis of Aplyviolene

The enantioselective total synthesis of the rearranged spongian diterpene aplyviolene has been completed in 14 steps from the known hydroazulenone 8. The key junction of the hydrocarbon and oxygenated fragments to form the critical C8 quaternary carbon stereocenter and set the stage for elaborating...

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Bibliographic Details
Main Authors: Overman, Larry E., Schnermann, Martin J.
Format: Artigo
Language:Inglês
Published: 2011
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3205941/
https://ncbi.nlm.nih.gov/pubmed/21936525
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208018s
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