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Tandem Rh-Catalysis: Decarboxylative β-Keto Acid and Alkyne Cross-Coupling
Herein, we describe a regioselective Rh-catalyzed decarboxylative cross-coupling of β–keto acids and alkynes to access branched γ,δ–unsaturated ketones. Rh-hydride catalysis enables the isomerization of an alkyne to generate a metal-allyl species that can undergo carbon-carbon bond formation. Ketone...
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| 出版年: | Chem Commun (Camb) |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4851867/ https://ncbi.nlm.nih.gov/pubmed/27043656 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc02522f |
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