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Diastereodivergent Reductive Cross Coupling of Alkynes Through Tandem Catalysis: Z- and E-Selective Hydroarylation of Terminal Alkynes

A diastereodivergent hydroarylation of terminal alkynes is accomplished using tandem catalysis. The hydroarylation allows highly selective synthesis of both E and Z diastereoisomers of aryl alkenes, from the same set of starting materials, using the same combination of palladium and copper catalysts...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Armstrong, Megan K., Goodstein, Madison B., Lalic, Gojko
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6693874/
https://ncbi.nlm.nih.gov/pubmed/30063341
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05113
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