Loading...
Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation
We report a Rh-catalyst for accessing olefins from primary alcohols by a C–C bond cleavage that results in dehomologation. This functional group interconversion proceeds by an oxidation-dehydroformylation enabled by N,N-dimethylacrylamide as a sacrificial acceptor of hydrogen gas. Alcohols with dive...
Saved in:
| Published in: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2018
|
| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6619493/ https://ncbi.nlm.nih.gov/pubmed/30084247 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b06069 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|