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Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation
We report a Rh-catalyst for accessing olefins from primary alcohols by a C–C bond cleavage that results in dehomologation. This functional group interconversion proceeds by an oxidation-dehydroformylation enabled by N,N-dimethylacrylamide as a sacrificial acceptor of hydrogen gas. Alcohols with dive...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6619493/ https://ncbi.nlm.nih.gov/pubmed/30084247 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b06069 |
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