Preparation and Protonation of Fe(2)(pdt)(CNR)(6), Electron-Rich Analogues of Fe(2)(pdt)(CO)(6)

The complexes Fe(2) (pdt)(CNR)(6) (pdt(2−) = CH(2)(CH(2)S(−))(2)) were prepared by thermal substitution of the hexacarbonyl complex with the isocyanides RNC for R = C(6)H(4)-4-OMe (1), C(6)H(4)-4-Cl (2), Me (3). These complexes represent electron-rich analogues of the parent Fe(2)(pdt)(CO)(6). Unlik...

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Publicado en:Inorg Chem
Main Authors: Zhou, Xiaoyuan, Barton, Bryan E., Chambers, Geoffrey M., Rauchfuss, Thomas B., Arrigoni, Federica, Zampella, Giuseppe
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4821816/
https://ncbi.nlm.nih.gov/pubmed/26999632
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b02789
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