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Isomerization of the hydride complexes [HFe(2)(SR)(2)(PR(3))(x)(CO)(6–)(x)](+) (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases()
The stepwise formation of bridging (μ-) hydrides of diiron dithiolates is discussed with attention on the pathway for protonation and subsequent isomerizations. Our evidence is consistent with protonations occurring at a single Fe center, followed by isomerization to a series of μ-hydrides. Protonat...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3476456/ https://ncbi.nlm.nih.gov/pubmed/20221534 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b910147k |
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