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Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges

The one-electron oxidations of a series of diiron(I) dithiolato carbonyls were examined to evaluate the factors that affect the oxidation state assignments, structures, and reactivity of these low-molecular weight models for the H(ox) state of the [FeFe]-hydrogenases. The propanedithiolates Fe(2)(S(...

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Auteurs principaux: Justice, Aaron K., De Gioia, Luca, Nilges, Mark J., Rauchfuss, Thomas B., Wilson, Scott R., Zampella, Giuseppe
Format: Artigo
Langue:Inglês
Publié: 2008
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2562777/
https://ncbi.nlm.nih.gov/pubmed/18620387
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic8007552
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