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Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges
The one-electron oxidations of a series of diiron(I) dithiolato carbonyls were examined to evaluate the factors that affect the oxidation state assignments, structures, and reactivity of these low-molecular weight models for the H(ox) state of the [FeFe]-hydrogenases. The propanedithiolates Fe(2)(S(...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2562777/ https://ncbi.nlm.nih.gov/pubmed/18620387 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic8007552 |
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