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Chemical and Biological Reduction of the Radical SAM Enzyme 7-Carboxy-7-deazaguanine Synthase
The radical S-adenosyl-l-methionine (SAM) superfamily is a large and growing group of enzymes that carry out complex radical-mediated transformations. A one-electron reduction of SAM via the +1 state of the cubane [4Fe-4S] cluster generates a 5′-deoxyadenosyl radical, which initiates turnover. The [...
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| Publicat a: | Biochemistry |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4774511/ https://ncbi.nlm.nih.gov/pubmed/25933252 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.5b00210 |
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