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Hydride Attack on a Coordinated Ferric Nitrosyl: Experimental and DFT Evidence for the Formation of a Heme Model-HNO Derivative

Heme-HNO species are crucial intermediates in several biological processes. To date, no well-defined Fe heme-HNO model compounds have been reported. Hydride attack on the cationic ferric [(OEP)Fe(NO)(5-MeIm)]OTf (OEP = octaethylporphy-rinato dianion) generates the Fe-HNO product that has been charac...

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Bibliografski detalji
Izdano u:J Am Chem Soc
Glavni autori: Abucayon, Erwin G., Khade, Rahul L., Powell, Douglas R., Zhang, Yong, Richter-Addo, George B.
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4736739/
https://ncbi.nlm.nih.gov/pubmed/26678216
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12008
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