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Hydride Attack on a Coordinated Ferric Nitrosyl: Experimental and DFT Evidence for the Formation of a Heme Model-HNO Derivative
Heme-HNO species are crucial intermediates in several biological processes. To date, no well-defined Fe heme-HNO model compounds have been reported. Hydride attack on the cationic ferric [(OEP)Fe(NO)(5-MeIm)]OTf (OEP = octaethylporphy-rinato dianion) generates the Fe-HNO product that has been charac...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4736739/ https://ncbi.nlm.nih.gov/pubmed/26678216 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b12008 |
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