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Not limited to Iron: A Cobalt Heme–NO Model Facilitates N–N Coupling with External NO in the Presence of a Lewis Acid to Generate N(2)O
Some bacterial heme proteins catalyze the coupling of two NO molecules to generate N(2)O. We previously reported that a heme Fe–NO model engages in this N–N bond-forming reaction with NO. We now demonstrate that (OEP)Co(II)(NO) similarly reacts with 1 equiv. of NO in the presence of the Lewis acids...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6901747/ https://ncbi.nlm.nih.gov/pubmed/31591802 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909137 |
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