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Not limited to Iron: A Cobalt Heme–NO Model Facilitates N–N Coupling with External NO in the Presence of a Lewis Acid to Generate N(2)O

Some bacterial heme proteins catalyze the coupling of two NO molecules to generate N(2)O. We previously reported that a heme Fe–NO model engages in this N–N bond-forming reaction with NO. We now demonstrate that (OEP)Co(II)(NO) similarly reacts with 1 equiv. of NO in the presence of the Lewis acids...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Abucayon, Erwin G., Khade, Rahul L., Powell, Douglas R., Zhang, Yong, Richter-Addo, George B.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6901747/
https://ncbi.nlm.nih.gov/pubmed/31591802
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201909137
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