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Over or under: Hydride attack at the metal versus the coordinated nitrosyl ligand in ferric nitrosyl porphyrins
Hydride attack at a ferric heme–NO to give an Fe–HNO intermediate is a key step in the global N-cycle. We demonstrate differential reactivity when six- and five-coordinate ferric heme-NO models react with hydride. Although Fe–HNO formation is thermodynamically favored from this reaction, Fe–H format...
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| Veröffentlicht in: | Dalton Trans |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5110368/ https://ncbi.nlm.nih.gov/pubmed/27801456 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6dt03860c |
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