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Intramolecular [4+2] Trapping of a Hexadehydro-Diels–Alder (HDDA) Benzyne by Tethered Arenes
We report here the efficient, intramolecular trapping in a Diels–Alder (DA) sense of thermally generated benzynes by one of two pendant arene rings. A more electron rich ring (p-methoxyphenyl) reacted substantially faster than a simple phenyl ring, which was in turn, slightly more reactive vs. a 4-c...
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| Publicado no: | Org Lett |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4729866/ https://ncbi.nlm.nih.gov/pubmed/25671804 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol5037024 |
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