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Mechanism of the Intramolecular Hexadehydro-Diels–Alder Reaction
Theoretical analysis of the mechanism of the intramolecular hexadehydro-Diels–Alder (HDDA) reaction, validated against prior and newly measured kinetic data for a number of different tethered yne-diynes, indicates that the reaction proceeds in a highly asynchronous fashion. The rate-determining step...
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| Veröffentlicht in: | J Org Chem |
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| Hauptverfasser: | , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4729778/ https://ncbi.nlm.nih.gov/pubmed/26270857 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01356 |
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