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Mechanism of the Intramolecular Hexadehydro-Diels–Alder Reaction

Theoretical analysis of the mechanism of the intramolecular hexadehydro-Diels–Alder (HDDA) reaction, validated against prior and newly measured kinetic data for a number of different tethered yne-diynes, indicates that the reaction proceeds in a highly asynchronous fashion. The rate-determining step...

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Bibliografiset tiedot
Julkaisussa:J Org Chem
Päätekijät: Marell, Daniel J., Furan, Lawrence R., Woods, Brian P., Lei, Xiangyun, Bendelsmith, Andrew J., Cramer, Christopher J., Hoye, Thomas R., Kuwata, Keith T.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2015
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4729778/
https://ncbi.nlm.nih.gov/pubmed/26270857
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01356
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