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Biochemical establishment and characterization of EncM's flavin-N5-oxide cofactor
The ubiquitous flavin-dependent monooxygenases commonly catalyze oxygenation reactions by means of a transient C4a-peroxyflavin. A recent study, however, suggested an unprecedented flavin-oxygenating species - proposed as the flavin-N5-oxide (Fl(N5[O])) - as key to an oxidative Favorskii-type rearra...
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| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4720136/ https://ncbi.nlm.nih.gov/pubmed/26067765 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b03983 |
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