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Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement
Flavoproteins catalyze a diversity of fundamental redox reactions and are one of the most studied enzyme families(1,2). As monooxygenases, they are universally thought to control oxygenation by means of a peroxyflavin species that transfers a single atom of molecular oxygen to an organic substrate(1...
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| Main Authors: | , , , , , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3844076/ https://ncbi.nlm.nih.gov/pubmed/24162851 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature12643 |
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