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Formal Synthesis of Premisakinolide A and C(19)-C(32) of Swinholide A via Site-Selective C-H Allylation and Crotylation of Unprotected Diols

[Image: see text] Using stereo- and site-selective C-H allylation and crotylation of unprotected diols, an intermediate in the synthesis of premisakinolide A (bistheonellic acid B) that was previously made in 16–27 (LLS) steps is now prepared in only 9 steps. This fragment also represents a synthesi...

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Bibliografske podrobnosti
izdano v:Org Lett
Main Authors: Shin, Inji, Krische, Michael J.
Format: Artigo
Jezik:Inglês
Izdano: 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4686429/
https://ncbi.nlm.nih.gov/pubmed/26375150
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02056
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