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Asymmetric Iridium Catalyzed C-C Coupling of Chiral Diols via Site-Selective Redox-Triggered Carbonyl Addition

Cyclometalated π-allyliridium C,O-benzoate complexes modified by axially chiral chelating phosphine ligands display a pronounced kinetic preference for primary alcohol dehydrogenation, enabling highly site-selective redox-triggered carbonyl additions of chiral primary-secondary 1,3-diols with except...

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Bibliografiske detaljer
Udgivet i:Top Curr Chem
Main Authors: Shin, Inji, Krische, Michael J.
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4716893/
https://ncbi.nlm.nih.gov/pubmed/26187028
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/128_2015_651
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