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Iridium Catalyzed C-C Coupling via Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Cyclohexadiene
[Image: see text] Under hydrogen auto-transfer conditions employing a catalyst derived from [Ir(cod)Cl](2) and BIPHEP, 1,3-cyclohexadiene (CHD) couples to benzylic alcohols 1a-9a to furnish carbonyl addition products 1c-9c, which appear as single diastereomers with variable quantities of regioisomer...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2860772/ https://ncbi.nlm.nih.gov/pubmed/18254642 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800159w |
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