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Extreme electric fields power catalysis in the active site of ketosteroid isomerase
Enzymes use protein architecture to impose specific electrostatic fields onto their bound substrates, but the magnitude and catalytic effect of these electric fields have proven difficult to quantify with standard experimental approaches. Using vibrational Stark effect spectroscopy, we found that th...
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| 出版年: | Science |
|---|---|
| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2014
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4668018/ https://ncbi.nlm.nih.gov/pubmed/25525245 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1259802 |
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