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The General Base in the Thymidylate Synthase Catalyzed Proton Abstraction

The enzyme thymidylate synthase (TSase), an important chemotherapeutic drug target, catalyzes the formation of 2′-deoxythymidine-5′-monophosphate (dTMP), a precursor of one of the DNA building blocks. TSase catalyzes a multi-step mechanism that includes the abstraction of a proton from the C5 of the...

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Detalhes bibliográficos
Publicado no:Phys Chem Chem Phys
Main Authors: Ghosh, Ananda K., Islam, Zahidul, Krueger, Jonathan, Abeysinghe, Don Thelma, Kohen, Amnon
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4624062/
https://ncbi.nlm.nih.gov/pubmed/25912171
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cp01246e
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