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An Umpolung Approach for the Chemoselective Arylation of Selenocysteine in Unprotected Peptides
[Image: see text] Herein we report an umpolung strategy for the bioconjugation of selenocysteine in unprotected peptides. This mild and operationally simple approach takes advantage of the electrophilic character of an oxidized selenocysteine (Se–S bond) to react with a nucleophilic arylboronic acid...
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| Gepubliceerd in: | J Am Chem Soc |
|---|---|
| Hoofdauteurs: | , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2015
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4613869/ https://ncbi.nlm.nih.gov/pubmed/26225900 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05447 |
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